A collection of experiments that demonstrate chemical concepts and processes.
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Making rayon

Demonstration

Cellulose, in the form of cotton wool or filter paper, is dissolved in a solution containing tetraamminecopper(II) ions to produce a viscous blue liquid. This liquid is injected into sulfuric acid with a syringe to form rayon fibres.
 

Lesson organisation


The demonstration takes up to one and a half hours, much of which is taken up by dissolving the cellulose. The time can be shortened to about 15 mins if the cellulose solution is prepared beforehand.

Chemicals

Basic copper carbonate (HARMFUL), 10 g

Concentrated 880 ammonia solution (CORROSIVE, DANGEROUS FOR THE ENVIRONMENT), 100 cm3

Sulfuric acid, about 1 M (IRRITANT), 500 cm3

Refer to Health & Safety and Technical notes section below for additional information.

Apparatus

Eye protection

Beakers (250 cm3), 2

Beaker (1 dm3)

Glass stirring rod

Plastic syringe (10 cm3 or 20 cm3) fitted with a hypodermic needle (Note 1)

Access to a fume cupboard

Access to a magnetic stirrer (optional) 

Cotton wool (about 2 cotton balls), 2 g (Note 2

Health & Safety and Technical notes


Read our standard health & safety guidance

Wear eye protection (goggles) and work in a fume cupboard. 

Basic copper carbonate, CuCO3.Cu(OH)2(s), (HARMFUL) - see CLEAPSS Hazcard.

Concentrated 880 ammonia solution, NH3(aq),  (CORROSIVE, DANGEROUS FOR THE ENVIRONMENT). Ammonia gas, NH3(g) (TOXIC), will diffuse from the solution. Work in a fume cupboard. See CLEAPSS Hazcards.

Sulfuric acid, H2SO4(aq), (IRRITANT) - see CLEAPSS Hazcard and CLEAPSS Recipe Book.

1 If a hypodermic needle is to be used, this must be kept well supervised e.g. in a locked cupboard, until needed and after use. Alternatively, a hypodermic needle need not be used, however the fibre produced will be less fine.

2 It is important that the cotton wool is pure cotton and does not contain any synthetic fibres. Two grams of filter paper, or even newspaper, can be used as an alternative. However, the best results are obtained with cotton wool.

3 Glassware can be cleaned with dilute ammonia solution.

Procedure


Before the demonstration
You can prepare a solution of cellulose before the demonstration to save time.

a Weigh 10 g of basic copper carbonate into one of the 250 cm3 beakers, and, working in a fume cupboard, add 100 cm3 of 880 ammonia solution.

b Stir (with a magnetic stirrer, if available) for two minutes, allow to settle and then decant the resulting deep blue solution – which contains tetraamminecopper(II) ions – into the second 250 cm3 beaker.

c Add bits of the finely shredded cotton wool, slowly and with stirring, until the solution has the consistency of shower gel. This uses about 1–1.5 g of the wool.

d Stir until there are no lumps, but avoid trapping any air bubbles in the liquid. Complete dissolution may take up to an hour.
 

The demonstration
a Withdraw a few cm3 of this viscous solution – which is called ‘viscose’ – into the plastic syringe, avoiding taking up any remaining lumps.

b Fit a hypodermic needle to the syringe and inject a stream of viscose under the surface of about 500 cm3 of the sulfuric acid in the 1 dm3 beaker.

c A thin blue rayon fibre will forms. This slowly turns white as the acid neutralises the alkaline tetraamminecopper(II) solution, and destroys the complex.

d After a few minutes, remove the rayon fibre carefully and wash under a stream of tap water and leave to dry on a filter paper. The fibre is likely to be relatively weak.

 

Teaching notes


You may not only prefer to make the viscose solution beforehand, but also form some rayon fibres using the syringe to have these in reserve in case the demonstration does not go according to plan.

Rayon is a so-called ‘regenerated fibre’ which was once called artificial silk. The polymer contains about 270 glucose units per molecule compared with cotton, which contains between 2000 and 10,000.

The first step in the demonstration is a reaction of basic copper carbonate with aqueous ammonia to form tetraamminecopper(II) ions:

CuCO3.Cu(OH)2.H2O(s) + 4NH3(aq) → CuCO3(s) + [Cu(NH3)4]2+(aq) + 2OH(aq) + H2O(l)

When the insoluble cellulose is added to this solution it is converted to a soluble complex compound. This in turn is converted into insoluble rayon once the pH is reduced to the acidic value found in molar sulfuric acid. Accordingly, rayon precipitates out when extruded into the acid. The blue colour quickly fades away after the copper(II) ions diffuse into the solution.

On an industrial level, the blue solution is passed through spinnerets and regenerated in a hardening bath that neutralises the product and removes the copper and ammonia.

‘Cuprammonium rayon’ is usually made in fine filaments that are used in blouses, lightweight summer dresses and in combination with cotton for textured fabrics.

The ‘cuprammonium process’ duplicated in this activity is one of the earliest methods used for producing rayon, but is less cost-effective now than some other more modern methods.

Rayon is used to manufacture carpets, tyre cords and surgical materials as well as clothing.

Health & Safety checked February 2008

 

Weblinks


About.com (Inventors) - scroll down for a brief history of rayon.

 

Page last updated on 01 January 2012